Distributed basis functions: II. A sum rule and further discussion


Karabulut H.

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, cilt.38, ss.2427-2442, 2005 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 38 Konu: 14
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1088/0953-4075/38/14/008
  • Dergi Adı: JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS
  • Sayfa Sayıları: ss.2427-2442

Özet

In a recent paper (Karabulut 2004 J. Phys. B: At. Mol. Opt. Phys. 37 3103), the author presented a formalism to evaluate performance of a distributed basis to span a given function. The key concept in the formalism is the representation power r (k, d) which is an effective measure of the completeness. In this paper a numerical application of this formalism to estimate the magnitude of the error in a variational problem is presented. The analysis in this application also allows us to discuss what happens in the limit of infinitely dense basis functions. A sum rule that the r(k, d) satisfies is derived. The sum rule explains the strange peaks and dips observed in some r (k, d) versus k curves given in that publication.