Fabrication and structural, electrical characterization of i-ZnO/n-ZnO nanorod homojunctions


YILMAZ Ş., BACAKSIZ E., POLAT İ., Atasoy Y.

CURRENT APPLIED PHYSICS, vol.12, no.5, pp.1326-1333, 2012 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 12 Issue: 5
  • Publication Date: 2012
  • Doi Number: 10.1016/j.cap.2012.03.021
  • Journal Name: CURRENT APPLIED PHYSICS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1326-1333
  • Keywords: i-n ZnO homojunction, (Na-Mg) co-doping, SEM, XRD, Temperature dependence of I-V characteristics, P-TYPE ZNO, WIDE TEMPERATURE-RANGE, SPRAY-PYROLYSIS METHOD, SCHOTTKY DIODES, THIN-FILMS, DOPED ZNO, BARRIER HEIGHT, ZINC-OXIDE, MAGNETIC-PROPERTIES, NANOWIRE ARRAYS
  • Karadeniz Technical University Affiliated: Yes

Abstract

Well-aligned ZnO nanorods were synthesized by a vapor phase transport method on ZnO buffer layer coated n-Si substrates. X-ray diffraction and scanning electron microscopy results showed that the deposited ZnO nanorods crystallize in the wurtzite structure and are highly textured with their c-axes normal to the substrate and show a clearly hexagonal morphology. A heavily compensated and intrinsic ZnO layer (i-ZnO) doped with both Mg and Na was deposited on the nominally undoped ZnO nanorods (which show a natural n-type behavior) to produce an i-ZnO/n-ZnO homojunction. The i-ZnO layer consisted of the grainy shape nano-crystallites with the wavy surface morphology. The current-voltage (I-V) characteristics of these structures in the temperature range of 150-300 K have been analyzed in the framework of standard thermionic emission (TE) theory with the assumption of a Gaussian distribution of the barrier heights. The values of zero bias barrier height (Phi(b0)) and ideality factor (n) were found to be strongly temperature dependent whereby n decreases while Phi(b0) increases with increasing temperature. The ln(I-0/T-2) vs q/kT plot shows a straight line behavior and the values of activation energy (E-a - Phi(b0)) and the Richardson constant (A*) determined from the intercept and slope of the plot were 0.926 eV and 2.61 x 10(-8) A cm(-2) K-2, respectively. This value of A* is much lower than the known value of 32 A cm(-2) K-2 for ZnO. Thus, a modified ln(I-0/T-2) - (sigma(2)(0)q(2)/2k(2)T(2)) vs. q/kT plot based on a Gaussian distribution of barrier heights was used which yields a mean barrier height ((Phi) over bar (b0)) and modified effective Richardson (A**) of 1.032 eV and 34.85 A cm(-2) K-2, respectively. This value of A** is much closer to the theoretical value of 32 A cm(-2) K-2 for ZnO. (C) 2012 Elsevier B.V. All rights reserved.