Synthesis and characterization of new (E,E)-dioxime and its homo and heterotrinuclear complexes containing dioxadithiadiazamacrobicycle moiety
POLYHEDRON, cilt.21, sa.19, ss.1865-1870, 2002 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 21 Sayı: 19
- Basım Tarihi: 2002
- Doi Numarası: 10.1016/s0277-5387(02)01022-7
- Dergi Adı: POLYHEDRON
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.1865-1870
- Karadeniz Teknik Üniversitesi Adresli: Evet
Özet
The new quinoxaline substituted (E,E)-dioxime (H2L) containing a dioxadithiadiazamacrobicycle has been synthesized from a 2,3-phenylenediamine attached mixed-donor-macrobicycle unit and cyanogen-di-N-oxide. The mononuclear Ni(II), BF2+-capped Ni(II) and heterotrinuclear Cu(I)Ni(II)Cu(I) complexes were prepared and their structures were confirmed elemental analysis, H-1, C-13 NMR, IR and FAB MS spectral data. (C) 2002 Published by Elsevier Science Ltd.