Novel metallophthalocyanines bearing 3-(p-chlorophenyl)-5-p-tolyl-4H-1,2,4-triazole bulky substituents by microwave irradiation

BEKİRCAN, OLCAY; BIYIKLIOĞLU, ZEKERİYA; ACAR, İRFAN; BEKTAS, Hakan; KANTEKİN, HALİT

doi:10.1016/j.jorganchem.2008.08.007

Novel metallophthalocyanines bearing 3-(p-chlorophenyl)-5-p-tolyl-4H-1,2,4-triazole bulky substituents by microwave irradiation

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BEKİRCAN O., BIYIKLIOĞLU Z., ACAR İ., BEKTAS H., KANTEKİN H.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol.693, pp.3425-3429, 2008 (SCI-Expanded)

Publication Type: Article / Article
Volume: 693
Publication Date: 2008
Doi Number: 10.1016/j.jorganchem.2008.08.007
Journal Name: JOURNAL OF ORGANOMETALLIC CHEMISTRY
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.3425-3429
Karadeniz Technical University Affiliated: Yes

Abstract

The synthesis of metallophthalocyanines [6-9; M = Ni(II), Zn(II), Co(II) and Cu(II)] with four 1,2,4-triazole units obtained from 4-{(4-chloro-2-fluorobenzyl)[3-(4-chlorophenyl)-5-(4-methylphenyl)-4H-1,2,4-triazol-4-yl] amino} phthalonitrile (5) in the presence of dimethylaminoethanol and the corresponding anhydrous metal salts is described. The thermal stabilities of the Pc compounds were determined by thermogravimetric analysis. The new compounds were characterized by a combination of IR, H-1 NMR, C-13 NMR, UV-Vis, elemental analysis. (C) 2008 Elsevier B.V. All rights reserved.