Novel metallophthalocyanines bearing 3-(p-chlorophenyl)-5-p-tolyl-4H-1,2,4-triazole bulky substituents by microwave irradiation

BEKİRCAN O., BIYIKLIOĞLU Z., ACAR İ., BEKTAS H., KANTEKİN H.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.693, ss.3425-3429, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 693
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1016/j.jorganchem.2008.08.007
  • Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.3425-3429
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

The synthesis of metallophthalocyanines [6-9; M = Ni(II), Zn(II), Co(II) and Cu(II)] with four 1,2,4-triazole units obtained from 4-{(4-chloro-2-fluorobenzyl)[3-(4-chlorophenyl)-5-(4-methylphenyl)-4H-1,2,4-triazol-4-yl] amino} phthalonitrile (5) in the presence of dimethylaminoethanol and the corresponding anhydrous metal salts is described. The thermal stabilities of the Pc compounds were determined by thermogravimetric analysis. The new compounds were characterized by a combination of IR, H-1 NMR, C-13 NMR, UV-Vis, elemental analysis. (C) 2008 Elsevier B.V. All rights reserved.