Novel metallophthalocyanines bearing 3-(p-chlorophenyl)-5-p-tolyl-4H-1,2,4-triazole bulky substituents by microwave irradiation


BEKİRCAN O., BIYIKLIOĞLU Z., ACAR İ., BEKTAS H., KANTEKİN H.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol.693, pp.3425-3429, 2008 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 693
  • Publication Date: 2008
  • Doi Number: 10.1016/j.jorganchem.2008.08.007
  • Journal Name: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.3425-3429

Abstract

The synthesis of metallophthalocyanines [6-9; M = Ni(II), Zn(II), Co(II) and Cu(II)] with four 1,2,4-triazole units obtained from 4-{(4-chloro-2-fluorobenzyl)[3-(4-chlorophenyl)-5-(4-methylphenyl)-4H-1,2,4-triazol-4-yl] amino} phthalonitrile (5) in the presence of dimethylaminoethanol and the corresponding anhydrous metal salts is described. The thermal stabilities of the Pc compounds were determined by thermogravimetric analysis. The new compounds were characterized by a combination of IR, H-1 NMR, C-13 NMR, UV-Vis, elemental analysis. (C) 2008 Elsevier B.V. All rights reserved.