Analysis of CeO<sub>2</sub>/SiO<sub>2</sub> double-layer thin film stack with antireflection effect for silicon solar cells

Kanmaz I., TOMAKİN M., ÜZÜM A.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, vol.35, no.22, 2024 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 35 Issue: 22
  • Publication Date: 2024
  • Doi Number: 10.1007/s10854-024-13245-5
  • Journal Name: JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Aerospace Database, Applied Science & Technology Source, Chemical Abstracts Core, Communication Abstracts, Compendex, Computer & Applied Sciences, INSPEC, MEDLINE, Metadex, Civil Engineering Abstracts
  • Karadeniz Technical University Affiliated: Yes

Abstract

This study introduces CeO2/SiO2 double-layer film stacks and its antireflection coating effect. Optical properties were analyzed by spectrophotometer measurements; surface morphology and cross-sections were observed by Scanning Electron Microscopy (SEM); elemental distributions and crystallographic properties were determined by Energy Dispersive Spectroscopy (EDS) and X-ray Diffraction (XRD) measurements. Average reflectance of single-layer 0.3MSiO(2), 0.6MSiO(2), and 0.3MCeO(2) thin films were 30.54%, 20.12%, and 14.23%, respectively. Average reflectance was decreased significantly down to 5.9% by 0.3MCeO(2)/0.6MSiO(2) double-layer thin films comparing to those of the results of single-layer films and bare silicon surface reflection (similar to 40%). Antireflective effect of the films on solar cells was estimated by simulation using the measured reflection data. Simulated solar cells indicate that 0.3MCeO(2)/0.6MSiO(2) double-layer antireflective coatings are capable to increase the efficiency significantly and conversion efficiency of 21.7% could be achieved.