Laser-Driven Rapid Synthesis of Metal-Organic Frameworks and Investigation of UV-NIR Optical Absorption, Luminescence, Photocatalytic Degradation, and Gas and Ion Adsorption Properties
Polymers, vol.16, no.2, 2024 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 16 Issue: 2
- Publication Date: 2024
- Doi Number: 10.3390/polym16020217
- Journal Name: Polymers
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Chemical Abstracts Core, Communication Abstracts, Compendex, Food Science & Technology Abstracts, INSPEC, Metadex, Directory of Open Access Journals, Civil Engineering Abstracts
- Keywords: adsorption, laser method, metal-organic framework, photocatalytic activity
- Karadeniz Technical University Affiliated: Yes
Abstract
In this study, we designed a platform based on a laser-driven approach for fast, efficient, and controllable MOF synthesis. The laser irradiation method was performed for the first time to synthesize Zn-based MOFs in record production time (approximately one hour) compared to all known MOF production methods with comparable morphology. In addition to well-known structural properties, we revealed that the obtained ZnMOFs have a novel optical response, including photoluminescence behavior in the visible range with nanosecond relaxation time, which is also supported by first-principles calculations. Additionally, photocatalytic degradation of methylene blue with ZnMOF was achieved, degrading the 10 ppm methylene blue (MB) solution 83% during 1 min of irradiation time. The application of laser technology can inspire the development of a novel and competent platform for a fast MOF fabrication process and extend the possible applications of MOFs to miniaturized optoelectronic and photonic devices.