The synthesis and properties of new metal-free and metallophthalocyanines containing four diloop macrocyclic moieties

Bilgin A., Ertem B., Gok Y.

SUPRAMOLECULAR CHEMISTRY, vol.18, no.4, pp.361-369, 2006 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 18 Issue: 4
  • Publication Date: 2006
  • Doi Number: 10.1080/10610270600650667
  • Journal Name: SUPRAMOLECULAR CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.361-369
  • Karadeniz Technical University Affiliated: Yes

Abstract

The synthesis and characterization of new metal-free (9) and metal-containing (Zn, Ni or Cu 10, 11, 12) derivatives of a symmetrically octasubstituted phthalocyanine derived from 21,22-dicyano-2,3,5,6,8,9,11, 12,15,17,18,25,26,28-tetradecahydro[1,4,7,12] benzodioxa-dithiacyclotetradeceno[6,7-b][1,4,7,10,13]benzopentaoxa-cyclopentadecene (7). which was synthesized in a multi-step reaction sequence, have been described. The novel compouds have been characterized by a combination of elemental analysis, H-1 and C-13 NMR, IR, UV-vis and MS spectral data.