The synthesis and properties of new metal-free and metallophthalocyanines containing four diloop macrocyclic moieties


Bilgin A., Ertem B. , Gok Y.

SUPRAMOLECULAR CHEMISTRY, cilt.18, ss.361-369, 2006 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 18 Konu: 4
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1080/10610270600650667
  • Dergi Adı: SUPRAMOLECULAR CHEMISTRY
  • Sayfa Sayıları: ss.361-369

Özet

The synthesis and characterization of new metal-free (9) and metal-containing (Zn, Ni or Cu 10, 11, 12) derivatives of a symmetrically octasubstituted phthalocyanine derived from 21,22-dicyano-2,3,5,6,8,9,11, 12,15,17,18,25,26,28-tetradecahydro[1,4,7,12] benzodioxa-dithiacyclotetradeceno[6,7-b][1,4,7,10,13]benzopentaoxa-cyclopentadecene (7). which was synthesized in a multi-step reaction sequence, have been described. The novel compouds have been characterized by a combination of elemental analysis, H-1 and C-13 NMR, IR, UV-vis and MS spectral data.