Synthesis and characterization of a new organo-soluble metal-free and metallophthalocyanines bearing flexible moieties


NAS A. , KANTEKİN H.

POLYHEDRON, cilt.30, ss.1085-1090, 2011 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 30 Konu: 6
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1016/j.poly.2011.01.005
  • Dergi Adı: POLYHEDRON
  • Sayfa Sayıları: ss.1085-1090

Özet

This paper describes a new symmetric metal-free phthalocyanine and its transition metal complexes which were prepared by a condensation of 1,2-dihydroacenaphthylen-1-ol 1 and 4-nitro phthalonitrile 2 with Co(II), Ni(II), Cu(II), and Zn(II) salts in 2-(dimethylamino)ethanol, respectively. The novel phthalocyanines bearing oxygen donor atoms on peripheral position have been characterized by IR, UV-Vis, H-1 NMR, C-13 NMR, Mass spectra and elemental analysis. The thermal behaviours of 4-8 were investigated by TG/DTA. (C) 2011 Elsevier Ltd. All rights reserved.