A new polymeric phthalocyanine containing 16-membered tetrathia macrocyclic moieties by microwave irradiation: Synthesis and characterization


KANTEKİN H. , DILBER G., BIYIKLIOĞLU Z.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.693, ss.1038-1042, 2008 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 693 Konu: 6
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1016/j.jorganchem.2007.12.025
  • Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Sayfa Sayıları: ss.1038-1042

Özet

Tetranitrile monomer (3) was synthesized by nucleophilic aromatic substitution of 1,5,9,13-tetrathiacyclohexadecane- 3,11-diol (1) onto 4-nitrophthalonitrile (2). The metal-free phthalocyanine polymer (4) was prepared by the reaction of a tetranitrile monomer with 4-({11-[3-cyano-4-(cyanomethyl) phenoxy]-1,5,9,13-tetrathiacyclohexadecan-3-yl}oxy) phthalonitrile in 2-(dimethylamino) ethanol. Ni(II), Co(II), Cu(I)-phthalocyanine polymers were prepared by the reaction of the tetranitrile compound with the chlorides of Ni(II), Co(II) and Cu(I) in DMAE. Zn(II)-phthalocyanine polymer was prepared by the reaction of the tetranitrile compound with the acetates of Zn(II) in DMAE. The new compounds were characterized by a combination of IR, (1)H NMR, (13)C NMR, UV-Vis, elemental analysis and MS spectral data. (C) 2007 Elsevier B.V. All rights reserved.