Synthesis and characterization of a new (E, E)-dioxime and its homo and heteronuclear complexes containing macrobicylic moieties

Mendil, D; Bilgin, A; Gok, Y; Senturk, HB

doi:10.1023/a:1021279728967

Synthesis and characterization of a new (E, E)-dioxime and its homo and heteronuclear complexes containing macrobicylic moieties

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Mendil D., Bilgin A., Gok Y., Senturk H.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, vol.43, pp.265-270, 2002 (SCI-Expanded)

Publication Type: Article / Article
Volume: 43
Publication Date: 2002
Doi Number: 10.1023/a:1021279728967
Journal Name: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.265-270
Karadeniz Technical University Affiliated: No

Abstract

A new N,N'-substituted diaminoglyoxime (H2L) containing a diazatetraoxa macrobicycle [2.2.2(B)] has been synthesized from an aromatic primary amine attached to the cryptand moiety and cyanogen-di-N-oxide. The BF2+-capped Co(III) and heterotri-nuclear complexes of the vic-dioxime were prepared. The new compounds were characterized by a combination of elemental analysis and H-1 NMR, C-13 NMR, IR and MS spectral data.