Synthesis and characterization of a new (E, E)-dioxime and its homo and heteronuclear complexes containing macrobicylic moieties

Mendil D., Bilgin A., Gok Y., Senturk H.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, vol.43, pp.265-270, 2002 (SCI-Expanded) identifier identifier


A new N,N'-substituted diaminoglyoxime (H2L) containing a diazatetraoxa macrobicycle [2.2.2(B)] has been synthesized from an aromatic primary amine attached to the cryptand moiety and cyanogen-di-N-oxide. The BF2+-capped Co(III) and heterotri-nuclear complexes of the vic-dioxime were prepared. The new compounds were characterized by a combination of elemental analysis and H-1 NMR, C-13 NMR, IR and MS spectral data.