Microwave-assisted synthesis and characterization of novel metal-free and metallophthalocyanines containing four 14-membered tetraaza macrocycles

Biyiklioglu, ZEKERİYA; Kantekin, HALİT; OEZIL, Musa

doi:10.1016/j.jorganchem.2007.02.013

Microwave-assisted synthesis and characterization of novel metal-free and metallophthalocyanines containing four 14-membered tetraaza macrocycles

Atıf İçin Kopyala

Biyiklioglu Z., Kantekin H., OEZIL M.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.692, sa.12, ss.2436-2440, 2007 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 692 Sayı: 12
Basım Tarihi: 2007
Doi Numarası: 10.1016/j.jorganchem.2007.02.013
Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.2436-2440
Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

The novel tetrasubstituted metal-free phthalocyanine (6) and metallophthalocyanines (7, 8) bearing four 14-membered tetraaza macrocycles moieties on peripheral positions have been synthesized by cyclotetramerization reaction of phthalonitrile derivative (5) in a multi-step reaction sequence. The new compounds were characterized by a combination of IR, H-1 NMR, C-13 NMR, UV-vis, elemental analysis and MS spectral data. (c) 2007 Elsevier B.V. All rights reserved.