Microwave-assisted synthesis and characterization of novel metal-free and metallophthalocyanines containing four 14-membered tetraaza macrocycles
JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.692, sa.12, ss.2436-2440, 2007 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 692 Sayı: 12
- Basım Tarihi: 2007
- Doi Numarası: 10.1016/j.jorganchem.2007.02.013
- Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.2436-2440
- Karadeniz Teknik Üniversitesi Adresli: Evet
Özet
The novel tetrasubstituted metal-free phthalocyanine (6) and metallophthalocyanines (7, 8) bearing four 14-membered tetraaza macrocycles moieties on peripheral positions have been synthesized by cyclotetramerization reaction of phthalonitrile derivative (5) in a multi-step reaction sequence. The new compounds were characterized by a combination of IR, H-1 NMR, C-13 NMR, UV-vis, elemental analysis and MS spectral data. (c) 2007 Elsevier B.V. All rights reserved.