Fluoro functional groups substituted cobalt(II), iron(II) phthalocyanines and their catalytic properties on benzyl alcohol oxidation

AKTAS A., ACAR İ., SAKA E. T., BIYIKLIOĞLU Z., KANTEKİN H.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, cilt.86, ss.183-190, 2016 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 86
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1007/s10847-016-0650-z
  • Dergi Adı: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.183-190
  • Anahtar Kelimeler: Phthalocyanine, Iron, Cobalt, Benzyl alcohol, Catalytic activity, Oxidation, HIGHLY SELECTIVE OXIDATION, LIQUID-PHASE OXIDATION, SPECTROSCOPIC CHARACTERIZATION, AROMATIC-COMPOUNDS, HYDROGEN-PEROXIDE, AEROBIC OXIDATION, METAL-FREE, CO(II), WATER, BENZALDEHYDE
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

In this study, phthalocyanine complexes (Co and Fe) bearing (2-{2-[3-(trifluoromethyl)phenoxy]ethoxy}ethoxy) groups at peripheral position were synthesized using the phthalonitrile derivative and characterized by IR, H-1-NMR, UV-Vis and mass spectrometry. Catalytic activity of Co(II) and Fe(II) phthalocyanines were investigated in the oxidation of benzyl alcohol with different oxygen sources. Determination of the optimal conditions for oxidation of benzyl alcohol, the catalytic reactions were carried out change the reaction temperature, oxidant/cat ratio, types of oxidants and subst./catalyst ratio.