Fluoro functional groups substituted cobalt(II), iron(II) phthalocyanines and their catalytic properties on benzyl alcohol oxidation


AKTAS A., ACAR İ. , SAKA E. T. , BIYIKLIOĞLU Z. , KANTEKİN H.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, vol.86, pp.183-190, 2016 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 86
  • Publication Date: 2016
  • Doi Number: 10.1007/s10847-016-0650-z
  • Title of Journal : JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Page Numbers: pp.183-190

Abstract

In this study, phthalocyanine complexes (Co and Fe) bearing (2-{2-[3-(trifluoromethyl)phenoxy]ethoxy}ethoxy) groups at peripheral position were synthesized using the phthalonitrile derivative and characterized by IR, H-1-NMR, UV-Vis and mass spectrometry. Catalytic activity of Co(II) and Fe(II) phthalocyanines were investigated in the oxidation of benzyl alcohol with different oxygen sources. Determination of the optimal conditions for oxidation of benzyl alcohol, the catalytic reactions were carried out change the reaction temperature, oxidant/cat ratio, types of oxidants and subst./catalyst ratio.