Metal-organic framework composites as potential materials for energy storage applications
Metal-Organic Framework Composites: Energy Storage, Catalysis, Adsorption and Drug Delivery, De Gruyter, ss.281-366, 2026
- Yayın Türü: Kitapta Bölüm / Araştırma Kitabı
- Basım Tarihi: 2026
- Doi Numarası: 10.1515/9783111574080-010
- Yayınevi: De Gruyter
- Sayfa Sayıları: ss.281-366
- Anahtar Kelimeler: energy storage performance, metal-organic framework (MOF), MOF-based composites, phase change materials (PCMS), supercapacitor and batteries
- Karadeniz Teknik Üniversitesi Adresli: Evet
Özet
Metal-organic frameworks (MOFs) possess distinctive structural characteristics, including elevated surface area, adjustable porosity, and chemical adaptability. The characteristics of MOFs render them significant candidates for energy storage applications. To enhance the energy storage efficiency of MOFs, the exploration of MOF-based composites and their derivatives has gained significance. MOFs are combined with conductive materials, such as carbon nanotubes, graphene, or polymers, to create energy storage devices such as supercapacitors, batteries, and phase change materials (PCMs). The structural advantages of MOFs make them promising components in supercapacitors. They provide fast ion transport and good capacitance in supercapacitors. Therefore, the use of MOF-based materials as electrode materials in supercapacitors greatly improves efficient and sustainable energy storage technologies. MOFs and composites using MOF-derived materials demonstrate enhanced electrical conductivity, stability, and mechanical strength, which are essential. The charge capacities, ion transport efficiency, and cycling stability provide MOF composites as great candidates for next-generation energy storage technologies in the energy sector. MOF composites demonstrate substantial charge storage capacity, excellent cycling stability, and scalable synthesis options, positioning them as formidable prospects to address the growing energy requirements of contemporary society. MOFs offer a practical solution for major problems with next-generation rechargeable batteries. MOFs may control parasitic reactions, enhance redox kinetics, and maintain stable capacities by using their increased porosity, adjustable active sites, and unique structural features. Their far-reaching impact on lithium-ion, lithium-sulfur, lithium-oxygen, and zinc-air systems is investigated in this part; in lithium-ion batteries, MOF-based coatings – including MIL-101-COOH – reduce negative by-products, improving safety and maintaining over 95% capacity at high temperatures. Fe-ZIF-8 and quasi-MOFs scavenge and catalyze polysulfides in lithium-sulfur batteries, thereby reducing shuttle effects for maximum long-term stability. Mn-MOF-74-FcA greatly increases discharge capacity and reversibility in lithium-oxygen batteries. Lastly, in zinc-air systems, MOF-derived spinel fer-rites (Ni0.6Fe2.4O4@NC) show amazing bifunctional behavior. These results highlight, in general, the MOF’s capacity to enable effective, durable, high-energy electrochemical storage. This study analyzes the synthesis methodologies, structural benefits, and current advancements in MOF composites for electrical and thermal energy storage, emphasizing its capacity to address the growing need for efficient and sustainable energy solutions. The growing interest in the energy storage capabilities of MOF-based composites underscores their distinct benefits, the problems related to their development, and their potential to advance energy storage technology. Future perspectives and challenges in optimizing the properties of MOFs are examined to enable them to lead further research.