Models for superoxide dismutases: Characterization of mononuclear Cu(II), Fe(III), and Mn(II) complexes with 4 ',5 '-bis(salicylideneimino)benzo-15-crown-5

Guner, S; Karabocek, SERDAR; KAKLIKKAYA, İSLAM

doi:10.1016/s0968-0896(98)00240-5

Models for superoxide dismutases: Characterization of mononuclear Cu(II), Fe(III), and Mn(II) complexes with 4 ',5 '-bis(salicylideneimino)benzo-15-crown-5

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Guner S., Karabocek S., KAKLIKKAYA İ.

BIOORGANIC & MEDICINAL CHEMISTRY, vol.7, no.2, pp.329-333, 1999 (SCI-Expanded)

Publication Type: Article / Article
Volume: 7 Issue: 2
Publication Date: 1999
Doi Number: 10.1016/s0968-0896(98)00240-5
Journal Name: BIOORGANIC & MEDICINAL CHEMISTRY
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.329-333
Karadeniz Technical University Affiliated: Yes

Abstract

Mononuclear Cu(II), Fe(III), and Mn(II) complexes with 4',5'-bis(salicylideneimino)benzo-15-crown-5, (SALH(2)), were characterized by elemental analysis, IR and UV-Vis spectroscopy and tested spectrometrically as catalysts for superoxide disproportionation by utilizing xanthine-xanthine oxidase (XXO) assays. The results indicate that the examined mononuclear com complexes are speculative potent superoxide dismutase mimics. (C) 1999 Elsevier Science Ltd. All rights reserved.