[Hg-2(mu-bpe)(mu-OAc)(2)(mu-SCN)(2)], a new two-dimensional coordination polymer involving three simultaneously bridging ligands: 1,2-bis(4-pyridyle)ethene, acetate, and thiocyanate

Morsali A., YILMAZ V. T., Kazak C.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, cilt.631, sa.9, ss.1577-1579, 2005 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 631 Sayı: 9
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1002/zaac.200400550
  • Dergi Adı: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1577-1579
  • Anahtar Kelimeler: mercury, trans-1,2-bis(4-pyridyle)ethene, coordination polymers, COMPLEXES
  • Karadeniz Teknik Üniversitesi Adresli: Hayır

Özet

A new mercury(II) complex of 1,2-bis(4-pyridyle)ethene (bpe) with anionic acetate and thiocyanate ligands has been synthesized and characterized by elemental analysis, IR, H-1 NMR and C-13 NMR spectroscopy. The single crystal X-ray analysis shows that the complex is a two-dimensional polymer with simultaneously bridging 1,2-bis(4-pyridyle)ethane, acetate and thiocyanate ligands and basic repeating dimeric [Hg-2(mu-bpe)(mu-OAc)(2)(mu-SCN)(2)] units. The two-dimensional system forms a three-dimensional network by packing via pi-pi stacking interactions.