PREPARATION OF MULTIPHASE BLOCK-COPOLYMERS BY REDOX POLYMERIZATION PROCESS .3. POLYMERIZATION OF METHYL-METHACRYLATE AND ACRYLAMIDE BY THE MN(III)POLY(ETHYLENE GLYCOL) REDOX SYSTEM

CAKMAK, I

doi:10.1002/apmc.1995.052240101

PREPARATION OF MULTIPHASE BLOCK-COPOLYMERS BY REDOX POLYMERIZATION PROCESS .3. POLYMERIZATION OF METHYL-METHACRYLATE AND ACRYLAMIDE BY THE MN(III)POLY(ETHYLENE GLYCOL) REDOX SYSTEM

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CAKMAK I.

ANGEWANDTE MAKROMOLEKULARE CHEMIE, vol.224, pp.1-8, 1995 (SCI-Expanded)

Publication Type: Article / Article
Volume: 224
Publication Date: 1995
Doi Number: 10.1002/apmc.1995.052240101
Journal Name: ANGEWANDTE MAKROMOLEKULARE CHEMIE
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.1-8
Karadeniz Technical University Affiliated: No

Abstract

Redox-initiated free-radical polymerization of methyl methacrylate (MMA) and acrylamide (AAm) with poly(ethylene glycol) (PEG) using Mn(III) as reduction agent was carried out to yield PMMA-block-PEG-block-PMMA and AAm-block-PEG-block-AAm triblock copolymers. The principal parameters (concentration of the reactants, temperature) affecting the synthesis were examined. Block copolymers were characterized by H-1-NMR and infrared spectroscopy.