PREPARATION OF MULTIPHASE BLOCK-COPOLYMERS BY REDOX POLYMERIZATION PROCESS .3. POLYMERIZATION OF METHYL-METHACRYLATE AND ACRYLAMIDE BY THE MN(III)POLY(ETHYLENE GLYCOL) REDOX SYSTEM

CAKMAK, I

doi:10.1002/apmc.1995.052240101

PREPARATION OF MULTIPHASE BLOCK-COPOLYMERS BY REDOX POLYMERIZATION PROCESS .3. POLYMERIZATION OF METHYL-METHACRYLATE AND ACRYLAMIDE BY THE MN(III)POLY(ETHYLENE GLYCOL) REDOX SYSTEM

CAKMAK I.

ANGEWANDTE MAKROMOLEKULARE CHEMIE, cilt.224, ss.1-8, 1995 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 224
Basım Tarihi: 1995
Doi Numarası: 10.1002/apmc.1995.052240101
Dergi Adı: ANGEWANDTE MAKROMOLEKULARE CHEMIE
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.1-8
Karadeniz Teknik Üniversitesi Adresli: Hayır

Özet

Redox-initiated free-radical polymerization of methyl methacrylate (MMA) and acrylamide (AAm) with poly(ethylene glycol) (PEG) using Mn(III) as reduction agent was carried out to yield PMMA-block-PEG-block-PMMA and AAm-block-PEG-block-AAm triblock copolymers. The principal parameters (concentration of the reactants, temperature) affecting the synthesis were examined. Block copolymers were characterized by H-1-NMR and infrared spectroscopy.