The peripheral and non-peripheral 2H-benzotriazole substituted phthalocyanines: Synthesis, characterization, photophysical and photochemical studies of zinc derivatives

Dilber G., Altunparmak H., Nas A., Kantekin H., Durmus M.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, vol.217, pp.128-140, 2019 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 217
  • Publication Date: 2019
  • Doi Number: 10.1016/j.saa.2019.01.095
  • Journal Name: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.128-140
  • Keywords: Metallophthalocyanines, Non-peripheral, Peripheral, Photophysical, Photochemical, Singlet oxygen, PHOTOSENSITIZED SINGLET OXYGEN, SUPRAMOLECULAR INTERACTION, QUANTUM YIELDS, INDIUM(III) PHTHALOCYANINES, SILICON PHTHALOCYANINES, ELECTRONIC ABSORPTION, GOLD NANOPARTICLE, METAL-FREE, FLUORESCENCE, INSIGHTS
  • Karadeniz Technical University Affiliated: Yes

Abstract

In this study, the novel 3-(1H-benzo[d][1,2,3] triazol-1-yl) methoxy substituted novel phthalonitrile compounds (2 and 6) were synthesized. Their non-peripheral and peripheral zinc (II) (3 and 7), manganese (III) (4 and 8) and copper (II) (5 and 9) phthalocyanine complexes were synthesized for the first time. These novel compounds were characterized by elemental analysis and different spectroscopic techniques such as FT-IR, UV-Vis, H-1 NMR, C-13 NMR and MALDI-TOF mass. Also, photochemical and photophysical properties of non-peripheral and peripheral substituted zinc (II) phthalocyanines (3 and 7) were investigated for determination of photodynamic therapy applications of these phthalocyanines. (C) 2019 Elsevier B.V. All rights reserved.