Two-dimensional supramolecular networks generated from weak Ag center dot center dot center dot C-py interactions: Synthesis, structural, thermal and fluorescence studies of silver(I) complexes of 5,5-diethylbarbiturato with pyridine-2-ylmethanol and 2,6-dimethoxypyridine

YILMAZ V. T., Soyer E., Buyukgungor O.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.694, sa.20, ss.3306-3311, 2009 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 694 Sayı: 20
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1016/j.jorganchem.2009.06.006
  • Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.3306-3311
  • Anahtar Kelimeler: 5,5-Diethylbarbiturate, Pyridine-2-ylmethanol, 2,6-Dimethoxypyridine, Supramolecular network, Ag center dot center dot center dot C interaction, CRYSTAL-STRUCTURES, COORDINATION POLYMERS, COPPER(II), LIGANDS, METALS, DESIGN, ZINC
  • Karadeniz Teknik Üniversitesi Adresli: Hayır

Özet

Two new silver(I) complexes [Ag(barb)(pym)]center dot H2O (1) and [Ag(barb)(dmpy)]center dot 1.5H(2)O (2) (barb = 5,5-diethylbarbiturate, pym = pyridine-2-ylmethanol and dmpy = 2,6-dimethoxypyridine) have been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. In both complexes, the silver(I) ions are linearly coordinated by the N atoms of a barb anion and a pym or a dmpy ligand, forming mononuclear species. The molecules of 1 and 2 are doubly bridged by N-H center dot center dot center dot O hydrogen bonds involving the barb moieties and these hydrogen-bonded dimers are assembled into two-dimensional layered networks through weak Ag center dot center dot center dot C-py (eta(1)) interactions of ca. 3.3 angstrom. Additionally, the thermal and fluorescent properties of these complexes are also investigated. (C) 2009 Elsevier B.V. All rights reserved.