Synthesis and characterization of novel vic-dioxime and its mononuclear complexes containing tetraazadioxamacrobicyclic moieties

ERTEM B., Gok Y., Ertas I. E., BIYIKLIOĞLU Z.

JOURNAL OF COORDINATION CHEMISTRY, cilt.61, sa.13, ss.2113-2121, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 61 Sayı: 13
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1080/00958970701885374
  • Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2113-2121
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

A (E, E)-dioxime, N,N'-bis(7-aminobenzo-17,23-dimethyl-4,11-dioxa-1,14,17,23-tetraazapentacyclo[12.10.10(0.5,10)]hexadiconta-1,5,7,12,14-pentane)diaminoglyoxime (H(2)L) has been synthesized from (E, E)-dichloroglyoxime and 7-aminobenzo-17,23-dimethyl-4,11-dioxa-1,14,17,23-tetraazapentacyclo[12.10.10(0.5,10)]hexadiconta-1,5,7,12,14-pentane which has been prepared from 7-nitro-17,23-dimethyl-4,11-dioxa-1,14,17,23-tetraazapentacyclo[12.10.10(0.5,10)]hexadiconta-1,5,7,12,14-pentane. A mononuclear Ni(II) complex with a metal : ligand ratio of 1 : 2 was prepared and then a Ni(II) complex bridged with BF(2)(+) was obtained by reaction with boron trifluoride etherate. The structure of the dioxime and its transition metal complexes are proposed according to elemental analysis, (1)H NMR, IR and mass spectral data.