The synthesis and characterization of new phthalocyanines containing hexaazadithia macrobicyclic moieties

Kantekin, HALİT; KILICASLAN, MELTEM; SAHINBAS, H.; GOK, Yasar

doi:10.1080/00958970600667063

The synthesis and characterization of new phthalocyanines containing hexaazadithia macrobicyclic moieties

Kantekin H., KILICASLAN M. B., SAHINBAS H. Z., GOK Y.

JOURNAL OF COORDINATION CHEMISTRY, cilt.59, sa.17, ss.1929-1935, 2006 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 59 Sayı: 17
Basım Tarihi: 2006
Doi Numarası: 10.1080/00958970600667063
Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.1929-1935
Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

The new metal-free and metallo phthalocyanines (4) and (5) bearing four tetrasubstituted hexaazadithia macrobicycles on peripheral positions, have been synthesized. Phthalonitrile (3) has been synthesized from the reaction of (1,3,6,9,11,14 hexaazatricyclo [12.2.1.1(6,9)]) (1) and 1,2-bis(2-iodomercaptoethyl)-4,5-dicyanobenzene (2). The new compounds were characterized by elemental analysis, and IR, H-1, C-13-NMR, UV-Visible and mass spectral data.