The synthesis and characterization of new phthalocyanines containing hexaazadithia macrobicyclic moieties

Kantekin H., KILICASLAN M. B., SAHINBAS H. Z., GOK Y.

JOURNAL OF COORDINATION CHEMISTRY, vol.59, no.17, pp.1929-1935, 2006 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 59 Issue: 17
  • Publication Date: 2006
  • Doi Number: 10.1080/00958970600667063
  • Journal Name: JOURNAL OF COORDINATION CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1929-1935
  • Karadeniz Technical University Affiliated: Yes

Abstract

The new metal-free and metallo phthalocyanines (4) and (5) bearing four tetrasubstituted hexaazadithia macrobicycles on peripheral positions, have been synthesized. Phthalonitrile (3) has been synthesized from the reaction of (1,3,6,9,11,14 hexaazatricyclo [12.2.1.1(6,9)]) (1) and 1,2-bis(2-iodomercaptoethyl)-4,5-dicyanobenzene (2). The new compounds were characterized by elemental analysis, and IR, H-1, C-13-NMR, UV-Visible and mass spectral data.