The synthesis and characterization of new metal-free and metallo phthalocyanines substituted with four dithiatetraoxa macrocyclic moieties

Kantekin H., RAKAP M., Misir M. N., GOEK H. Z., Acar I.

JOURNAL OF COORDINATION CHEMISTRY, vol.60, no.18, pp.1965-1972, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 60 Issue: 18
  • Publication Date: 2007
  • Doi Number: 10.1080/00958970701217412
  • Journal Name: JOURNAL OF COORDINATION CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1965-1972
  • Karadeniz Technical University Affiliated: Yes

Abstract

New metal-free phthalocyanine ( 7) fused symmetrically in peripheral positions with four dithiatetraoxa macrocycles, has been synthesized by cyclotetramerization of the isoindoline-diimine derivative of macrocyclic 6. Metallophthalocyanine ( 8) was synthesized by reaction of phthalonitrile derivative ( 5) with anhydrous nickel( II) chloride. The new compounds were characterized by elemental analysis, H-1 and C-13-NMR, IR UV-Vis and mass spectroscopies.