Kinetic study of vinyl polymerization with a new oligo azo peroxidic initiator

Volga C., HAZER B., TORUL O.

EUROPEAN POLYMER JOURNAL, cilt.33, sa.6, ss.907-912, 1997 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 33 Sayı: 6
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1016/s0014-3057(96)00181-4
  • Dergi Adı: EUROPEAN POLYMER JOURNAL
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.907-912
  • Karadeniz Teknik Üniversitesi Adresli: Hayır

Özet

Oligo (4,4'-azobis-cyanopentanoyl-5-peroxy-2,5-dimethyl-n-hexylperoxide), Lu-Ab, was synthesized by the interfacial condensation of 4,4'-azobis-(4-cyanopentanoyl chloride) with 2,5-dimethyl-2,5-dihydroperoxyhexane in the presence of a base. The molecular weight of the initiator was determined to be 1586 g/mol by gel permeation chromatography (GPC). Oligo-azoperoxide, Lu-Ab, was characterized by infrared and nuclear magnetic resonance spectroscopies.