Gamma Radiation Shielding Efficiency of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymer Nanocomposites Doped Arsenic(III) Oxide and BoronNitride Nanoparticles


Ortaç B., Başkan T., Mutlu S., Savaşkan Yılmaz S., Yılmaz A. H.

POLYMERS, cilt.17, sa.3330, ss.17243330-17243372, 2025 (SCI-Expanded)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 17 Sayı: 3330
  • Basım Tarihi: 2025
  • Dergi Adı: POLYMERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
  • Sayfa Sayıları: ss.17243330-17243372
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

In recent years, polymer-based hybrid nanocomposites have emerged as promising

alternatives to traditional heavy metal shields due to their low density, flexibility, and

environmental safety. In this study, the synthesis of PS-PEG copolymers and the gamma

radiation-shielding properties of PS-PEG/As₂O₃, PS-PEG/BN, and PS-PEG/As₂O₃/BN

Nanocomposites with different compositions are investigated. The goal is to find the

optimal nanocomposite composition for gamma radiation shielding and dosimetry.

Therefore, the mass attenuation coefficient (MAC), linear attenuation coefficient (LAC),

half-value layer (HVL), tenth-value layer (TVL), effective atomic number, mean free path

(MFP), radiation shielding efficiency (RPE), electron density, and specific gamma-ray

constant were presented. Gamma rays emitted by the Eu source were detected by a high-purity

germanium (HPGe) detector device. GammaVision was used to analyze the given

data. Photon energy was in the vicinity of 121.8–1408.0 keV. The MAC values in XCOM

Simulation tools were used to compute. Gamma-shielding efficiency was increased by an

increased number of NPs at a smaller photon energy. At 121.8 keV, the HVL of a

composite with 70 wt% As₂O₃ NPs is 2.00 cm, which is comparable to the HVL of lead

(0.56 cm) at the same energy level. Due to the increasing need for lightweight, flexible,

and lead-free shielding materials, PS-b-PEG copolymer-based nanocomposites reinforced

with arsenic oxide and BN NPs will be materials of significant interest for next-generation

radiation protection applications.