Tetra(3-(1,5-diphenyl-4,5-dihydro-1H-pyrazol-3-yl) phenoxy) substituted cobalt, iron and manganese phthalocyanines: Synthesis and electrochemical analysis

Nas A., Bıyıklıoğlu Z., Fandaklı S., Sarkı G., Yalazan H., Kantekin H.

INORGANICA CHIMICA ACTA, cilt.466, ss.86-92, 2017 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 466
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1016/j.ica.2017.05.050
  • Dergi Adı: INORGANICA CHIMICA ACTA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.86-92
  • Anahtar Kelimeler: Metallophthalocyanines, Electrochemistry, Spectroelectrochemical, Square wave voltammetry, Manganese, Electropolymerization
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

This work reports on the synthesis, characterization of new symmetrical substituted cobalt (II) (4), iron (II) (5) and manganese (III) (6) phthalocyanines bearing tetra 3-(1,5-diphenyl-4,5-dihydro-1H-pyrazol-3yl) phenoxy groups and electrochemical properties of 4-6. The new compounds (3-6) have been characterized by IR, NMR spectroscopy, electronic spectroscopy and mass spectroscopic techniques. Electrochemical studies of cobalt (II) (4), iron (II) (5) and manganese (III) (6) phthalocyanines were examined by using cyclic voltammetry (CV) and square wave voltammetry (SWV) techniques. Voltammetric analyses of phthalocyanines supported the proposed structure of the complexes. Electrochemical studies reveal that all phthalocyanines gave metal and ligand based reduction process during the cathodic potential scans, but they were electropolymerized on the working electrode during the anodic potential scan. (c) 2017 Elsevier B.V. All rights reserved.