Synthesis and electrochemical properties of peripheral, non-peripheral tetra [2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] substituted cobalt(II), manganese(III) phthalocyanines

KELES T., BIYIKLIOĞLU Z., GULTEKIN E., BEKİRCAN O.

INORGANICA CHIMICA ACTA, vol.487, pp.201-207, 2019 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 487
  • Publication Date: 2019
  • Doi Number: 10.1016/j.ica.2018.12.010
  • Journal Name: INORGANICA CHIMICA ACTA
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.201-207
  • Keywords: Synthesis, Phthalocyanine, 1,2,4-Triazol, Electrochemistry, MICROWAVE-ASSISTED SYNTHESIS, SPECTROELECTROCHEMICAL PROPERTIES, METAL-FREE, METALLOPHTHALOCYANINES, ZINC(II), ELECTROPOLYMERIZATION, COPPER(II), MOIETIES, THERAPY
  • Karadeniz Technical University Affiliated: Yes

Abstract

In this study, 4-[2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy]phthalonitrile ET-CN, 3-[2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy]phthalonitrile n-ET-CN and cobalt(II), manganese(III) phthalocyanines bearing [2(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] group at peripheral, non-peripheral positions were synthesized for the first time. The new compounds have been characterized by FT-IR, NMR (only for ET-CN, n-ET-CN), mass and UV-Vis spectroscopy (except ET-CN, n-ET-CN) techniques. Electrochemistry of cobalt(II), manganese(III) phthalocyanines bearing [2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] group at peripheral, non-peripheral positions were examined by using cyclic voltammetry.