The synthesis and characterization of a new tetraoxime and its dinuclear complexes

Kantekin H., GOK Y.

JOURNAL OF COORDINATION CHEMISTRY, cilt.46, sa.3, ss.283-290, 1999 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 46 Sayı: 3
  • Basım Tarihi: 1999
  • Doi Numarası: 10.1080/00958979908048473
  • Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.283-290
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

A novel bis(dioxime) (H4L) containing the hexaoxa macrocyclic moiety has been synthesized from the reaction of tetraaminodibenzo-18-crown-6 (1) and 2,3-butanedione monooxime (2). An octahedral cobalt(III) complex of this ligand was prepared by the oxidation of the cobalt(II) complex. The BF2 bridged cobalt(III) complex was achieved by using the hydrogen bridged cobalt(III) complex and boron trifluoride. The structures of the bis(dioxime) and its complexes are proposed according to elemental analysis, H-1 and C-13 NMR, IR and MS data.