AXIAL-LIGATION AND MACROCYCLIZATION OF NOVEL (E,E)-DIOXIMES OF NICKEL(II), PALLADIUM(II), PLATINUM(II) AND COBALT(III)

GOK Y., KARABOCEK S., KANTEKIN H.

TRANSITION METAL CHEMISTRY, vol.20, no.3, pp.234-238, 1995 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 20 Issue: 3
  • Publication Date: 1995
  • Doi Number: 10.1007/bf00143483
  • Journal Name: TRANSITION METAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.234-238
  • Karadeniz Technical University Affiliated: No

Abstract

The synthesis and characterization of new Ni-II, Pd-II, Pt-II and Co-III complexes, with the BF2+-bridged, bis(alpha-dioximato) ligands are described. The initially formed six-coordinate hydrogen-bonded macrocycles, were used as metal templates to prepare the corresponding BF2+-capped macrocycles. The complexes were characterized by H-1-n.m.r. and i.r, spectroscopy, and by elemental analysis.