AXIAL-LIGATION AND MACROCYCLIZATION OF NOVEL (E,E)-DIOXIMES OF NICKEL(II), PALLADIUM(II), PLATINUM(II) AND COBALT(III)


GOK Y., KARABOCEK S. , KANTEKIN H.

TRANSITION METAL CHEMISTRY, cilt.20, ss.234-238, 1995 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 20 Konu: 3
  • Basım Tarihi: 1995
  • Doi Numarası: 10.1007/bf00143483
  • Dergi Adı: TRANSITION METAL CHEMISTRY
  • Sayfa Sayıları: ss.234-238

Özet

The synthesis and characterization of new Ni-II, Pd-II, Pt-II and Co-III complexes, with the BF2+-bridged, bis(alpha-dioximato) ligands are described. The initially formed six-coordinate hydrogen-bonded macrocycles, were used as metal templates to prepare the corresponding BF2+-capped macrocycles. The complexes were characterized by H-1-n.m.r. and i.r, spectroscopy, and by elemental analysis.