Synthesis and characterization of new metal-free and metallophthalocyanines peripherally fused to four 15-membered tetraoxamonoazamacrocycles by microwave irradiation

KANTEKİN, HALİT; BIYIKLIOĞLU, ZEKERİYA; CELENK, Elif

doi:10.1016/j.inoche.2008.02.028

Synthesis and characterization of new metal-free and metallophthalocyanines peripherally fused to four 15-membered tetraoxamonoazamacrocycles by microwave irradiation

KANTEKİN H., BIYIKLIOĞLU Z., CELENK E.

INORGANIC CHEMISTRY COMMUNICATIONS, cilt.11, sa.6, ss.633-635, 2008 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 11 Sayı: 6
Basım Tarihi: 2008
Doi Numarası: 10.1016/j.inoche.2008.02.028
Dergi Adı: INORGANIC CHEMISTRY COMMUNICATIONS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.633-635
Anahtar Kelimeler: phthalocyanine, tetraoxamonoazamacrocycle, phthalonitrile, macrocyclization, metallophthalocyanine, ASSISTED SYNTHESIS, TETRATHIAFULVALENE UNITS, PHTHALOCYANINES, MACROCYCLES, LIGANDS
Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

The synthesis and characterization of new metal-free (4) and metallophthalocyanines (5, 6, 7 and 8) substituted four 15-membered tetraoxamonoaza macrocycles from 7-[(4-methylphenyl)sulfonyl]-2,3,6,7,8,9,11,12-octahydro-5H-1,4,10,13,7- benzotetraoxazacyclopen tadecine-15,16-dicarbonitrile (3) is described. The new compounds were characterized by a combination of IR, (1)H NMR, (13)C NMR, UV-vis, elemental analysis and MS spectral data. (C) 2008 Elsevier B.V. All rights reserved.