Synthesis and characterization of new metal-free and metallophthalocyanines peripherally fused to four 15-membered tetraoxamonoazamacrocycles by microwave irradiation

KANTEKİN H., BIYIKLIOĞLU Z., CELENK E.

INORGANIC CHEMISTRY COMMUNICATIONS, vol.11, no.6, pp.633-635, 2008 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 11 Issue: 6
  • Publication Date: 2008
  • Doi Number: 10.1016/j.inoche.2008.02.028
  • Journal Name: INORGANIC CHEMISTRY COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.633-635
  • Keywords: phthalocyanine, tetraoxamonoazamacrocycle, phthalonitrile, macrocyclization, metallophthalocyanine, ASSISTED SYNTHESIS, TETRATHIAFULVALENE UNITS, PHTHALOCYANINES, MACROCYCLES, LIGANDS
  • Karadeniz Technical University Affiliated: Yes

Abstract

The synthesis and characterization of new metal-free (4) and metallophthalocyanines (5, 6, 7 and 8) substituted four 15-membered tetraoxamonoaza macrocycles from 7-[(4-methylphenyl)sulfonyl]-2,3,6,7,8,9,11,12-octahydro-5H-1,4,10,13,7- benzotetraoxazacyclopen tadecine-15,16-dicarbonitrile (3) is described. The new compounds were characterized by a combination of IR, (1)H NMR, (13)C NMR, UV-vis, elemental analysis and MS spectral data. (C) 2008 Elsevier B.V. All rights reserved.