Synthesis and characterization of one-dimensional coordination polymers, [M(sac)(2)(mu-pyz)(H(2)O)(2)](n) [M=Zn(II), Cd(II), pyz =pyrazine, and sac = saccharinate]

YILMAZ V. T., Senel E., Kazak C.

JOURNAL OF COORDINATION CHEMISTRY, cilt.61, sa.16, ss.2675-2682, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 61 Sayı: 16
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1080/00958970801986783
  • Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2675-2682
  • Anahtar Kelimeler: saccharinate, pyrazine, coordination polymer, one-dimensional chain, crystal structure, COMPLEXES, CADMIUM(II), MOLECULES
  • Karadeniz Teknik Üniversitesi Adresli: Hayır

Özet

Two new coordination polymers, [M(sac)(2)(mu-pyz)(H(2)O)(2)]n [M=Zn(II)(1), Cd(II)(2), pyz =pyrazine, and sac =saccharinate], have been prepared and characterized by elemental analysis, FTIR spectroscopy, thermal analysis and single crystal X-ray diffraction. Both complexes are isomorphous and crystallize in the triclinic P (1) over bar space group. The metal(II) ions are octahedrally coordinated by two sac, two aqua and two pyz ligands. The sac ligands are N-coordinated, while the pyz ligands are bridges between the metal centers, leading to one-dimensional linear chains. Intra-chain M-M separations in 1 and 2 are 7.218 and 7.498 angstrom, respectively. The individual chains are linked by strong OW-H center dot center dot center dot O(sac) hydrogen bonds into two-dimensional layers, which are further assembled into three-dimensional supramolecular networks by aromatic pi(sac)center dot center dot center dot pi(sac) stackings interactions.