The photo-physicochemical properties of an octa-substituted zinc phthalocyanine containing 1,2,4-triazole moieties


Nas A.

JOURNAL OF COORDINATION CHEMISTRY, vol.69, no.8, pp.1326-1336, 2016 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 69 Issue: 8
  • Publication Date: 2016
  • Doi Number: 10.1080/00958972.2016.1161758
  • Title of Journal : JOURNAL OF COORDINATION CHEMISTRY
  • Page Numbers: pp.1326-1336

Abstract

4,5-Bis(2-(4-(4-methoxybenzylamino)-5-oxo-3-p-tolyl-4,5-dihydro-1H-1,2,4-triazol-1-yl)ethoxy)-substituted zinc(II) phthalocyanine (4) was synthesized from a phthalonitrile derivative (3). The compounds were characterized by several spectral methods such as electronic absorption, FT-IR, H-1 NMR, C-13 NMR, mass spectrometry, and elemental analyses. The photophysical and the photochemical properties of 4 were investigated in DMSO and DMF. The solvent effect on the photochemical and photophysical properties for 4 is also discussed.