Microwave assisted synthesis and characterization of novel metal-free and metallophthalocyanines containing four pyridyl groups


Biyiklioglu Z. , Kantekin H.

TRANSITION METAL CHEMISTRY, cilt.32, ss.851-856, 2007 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 32 Konu: 7
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1007/s11243-007-0212-8
  • Dergi Adı: TRANSITION METAL CHEMISTRY
  • Sayfa Sayıları: ss.851-856

Özet

The novel tetrasubstituted metal-free phthalocyanine (4) and metallophthalocyanines (5, 6, 7 and 8) bearing four pyridyl group moieties on peripheral positions have been synthesized by cyclotetramerization of the phthalonitrile derivative (3) in a multi-step reaction sequence. The new compounds were characterized by a combination of elemental analysis, H-1- and C-13-n.m.r., i.r., U.V.-vis and m.s. spectral data.