SEPARATION AND PRECONCENTRATION OF COPPER IN ENVIRONMENTAL SAMPLES ON AMBERLITE XAD-8 RESIN AFTER COMPLEXATION WITH A CARBOTHIOAMIDE DERIVATIVE

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Elvan H., Ozdes D., DURAN C., Sahin D., Tufekci M., Bahadir Z.

QUIMICA NOVA, cilt.36, sa.6, ss.831-835, 2013 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 36 Sayı: 6
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1590/s0100-40422013000600016
  • Dergi Adı: QUIMICA NOVA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.831-835
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

A new solid phase extraction (SPE) method has been developed for the selective separation and preconcentration of Cu (II) ions in food and water samples prior to its flame atomic absorption spectrometry determination. The method is based on the adsorption of the Cu(II)-2-{[4-Amino-3-(4-methylphenyl-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl]acetyl}-N-phenyl hydrazinecarbothioamide complex on Amberlite XAD-8 resin. The metal complex retained on the resin was eluted with 7.5 mL of 2.0 mol L-1 HCl in acetone. The optimum conditions for the SPE of Cu(II) ions were investigated, and the method was subsequently applied to sea water, stream water, rice, tea, and tobacco samples for the determination of Cu(II) levels.