Photophysical and photochemical study on the tetra 4-isopropylbenzyloxy substituted phthalocyanines

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YALCIN I., Yanik H., Akcay H. T., DEĞİRMENCİOĞLU İ., Durmus M.

JOURNAL OF LUMINESCENCE, vol.192, pp.739-744, 2017 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 192
  • Publication Date: 2017
  • Doi Number: 10.1016/j.jlumin.2017.07.062
  • Journal Name: JOURNAL OF LUMINESCENCE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.739-744
  • Karadeniz Technical University Affiliated: Yes

Abstract

In this study, the novel peripherally tetra 4-isopropylbenzyloxy substituted metal-free (4) zinc(II) (5) and oxotitanium (IV) (6) phthalocyanine complexes were synthesized. Furthermore, the axially 4-isopropylbenzyloxy substituted silicon(IV) phthalocyanine derivative (7) was also synthesized. These novel compounds were characterized by different spectroscopic methods such as FT-IR, 1H NMR, UV–vis and mass. The spectroscopic, photophysical and photochemical properties including electronic absorption, steady state fluorescence, singlet oxygen generation and photostability were studied in toluene.

Bu çalışmada yeni periferik olarak tetra 4-izopropilbenziloksi ikame edilmiş metal içermeyen (4) çinko (II) (5) ve oksotitanyum (IV) (6) ftalosiyanin kompleksleri sentezlenmiştir. Ayrıca eksenel olarak 4-izopropilbenziloksi ikameli silikon (IV) ftalosiyanin türevi (7) de sentezlenmiştir. Bu yeni bileşikler karakterize edildi
FT-IR, 1H NMR, UV-vis ve kütle gibi farklı spektroskopik yöntemlerle. Tolüen içinde elektronik absorpsiyon, kararlı durum floresan, singlet oksijen üretimi ve fotostabilite gibi spektroskopik, fotofiziksel ve fotokimyasal özellikler incelendi.