JOURNAL OF LUMINESCENCE, vol.192, pp.739-744, 2017 (SCI-Expanded)
In this study, the novel peripherally tetra 4-isopropylbenzyloxy substituted metal-free (4) zinc(II) (5) and oxotitanium (IV) (6) phthalocyanine complexes were synthesized. Furthermore, the axially 4-isopropylbenzyloxy substituted silicon(IV) phthalocyanine derivative (7) was also synthesized. These novel compounds were characterized by different spectroscopic methods such as FT-IR, 1H NMR, UV–vis and mass. The spectroscopic, photophysical and photochemical properties including electronic absorption, steady state fluorescence, singlet oxygen generation and photostability were studied in toluene.
Bu çalışmada yeni periferik olarak tetra 4-izopropilbenziloksi ikame edilmiş metal içermeyen (4) çinko (II) (5) ve oksotitanyum (IV) (6) ftalosiyanin kompleksleri sentezlenmiştir. Ayrıca eksenel olarak 4-izopropilbenziloksi ikameli silikon (IV) ftalosiyanin türevi (7) de sentezlenmiştir. Bu yeni bileşikler karakterize edildi
FT-IR, 1H NMR, UV-vis ve kütle gibi farklı spektroskopik yöntemlerle. Tolüen içinde elektronik absorpsiyon, kararlı durum floresan, singlet oksijen üretimi ve fotostabilite gibi spektroskopik, fotofiziksel ve fotokimyasal özellikler incelendi.