The mass attenuation coefficients for the elements Co, Cu and Ag and a thin film of CoCuAg alloy were measured in the energy range 4.029-38.729 keV. Effective atomic numbers and electron densities were calculated by using these coefficients. The energies were obtained by using secondary targets that were irradiated with gamma-ray photons of Am-241. The x-rays were counted by using a Canberra Ultra-LEGe detector with a resolution of 150 eV at 5.9 keV. The results were compared with theoretical calculated values and fairly good agreement was found between them within an average experimental error. The mass attenuation coefficients, effective atomic numbers and electron densities were plotted versus photon energy.