The synthesis and characterization of novel porphyrazines containing 5H-dibenz[b,f]azepine units

Karadeniz H., Gok Y.

DYES AND PIGMENTS, vol.77, no.2, pp.351-356, 2008 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 77 Issue: 2
  • Publication Date: 2008
  • Doi Number: 10.1016/j.dyepig.2007.06.002
  • Journal Name: DYES AND PIGMENTS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.351-356
  • Karadeniz Technical University Affiliated: Yes


The synthesis of novel metal-free (H(2)Pz) and metalloporphyrazines (MgPz), peripherally substituted with eight 5H-dibenz[b,f]azepine was performed by the cyclotetramerization of 1,5-bis(dibenz[b,f]azepinepropylthio)maleonitrile which was synthesized from 5H-dibenz[b,f]azepine and 1,10-diiodo-5,6-dicyano-4,7-dithia-5-decene. The new compounds were characterized by elemental analysis, H-1 NMR, C-13 NMR, IR, UV-vis and mass spectral data. (D 2007 Published by Elsevier Ltd.