Sonochemical syntheses and characterization of a new nano-sized 2-D lead(II) coordination polymer as precursor for preparation of PbBr(OH) nano-structure


Sadeghzadeh H., Morsali A., YILMAZ V. T. , Buyukgungor O.

JOURNAL OF COORDINATION CHEMISTRY, vol.63, no.19, pp.3423-3430, 2010 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 63 Issue: 19
  • Publication Date: 2010
  • Doi Number: 10.1080/00958972.2010.511202
  • Journal Name: JOURNAL OF COORDINATION CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.3423-3430
  • Keywords: Nano-structure, Coordination polymer, Lead(II), Crystal structure, RAY-POWDER DIFFRACTION, BISMUTH OXIDE, HYDROTHERMAL PROCESS, CRYSTAL-STRUCTURE, NANOSTRUCTURES, MICROCRYSTALS, COMPLEXES, GROWTH
  • Karadeniz Technical University Affiliated: No

Abstract

Nano-particles of a new 2-D Pb(II) coordination polymer, [Pb(4-pyc)(Br)(H2O)]n (1) (4-Hpyc = 4-pyridinecarboxylic acid), were synthesized by a sonochemical method. Crystal structure of 1 was determined by X-ray crystallography. The nano-particles were characterized by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy, and elemental analyses. PbBr(OH) nano-structure was obtained by the calcination of nano-particles of 1 at 400 degrees C.