trans-bis(ethylenediamine)bis(p-nitrobenzoxasulfamato)copper(II)

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Atıf İçin Kopyala

Kazak C., YILMAZ V. T., Yazicilar T.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.60, 2004 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 60
• Basım Tarihi: 2004
• Doi Numarası: 10.1107/s1600536804008773
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Karadeniz Teknik Üniversitesi Adresli: Hayır

Özet

The structure of trans-[Cu(nbs)(2)(en)(2)] [nbs is the p-nitrobenzoxasulfamate anion (C6H3N2O5S)(-) and en is ethylenediamine, C2H8N2] consists of neutral molecules. The Cu2+ ion occupies an inversion centre and exhibits an elongated distorted octahedral geometry, with two monodentate nbs anions and two bidentate en ligands. Both nbs ligands are O-coordinated via an O atom of the nitro group. The crystal structure is stabilized by hydrogen bonds and weak aromatic pi-pi stacking interactions between the benzene rings of nbs ligands, forming a three-dimensional network.