Synthesis and characterization of novel metal-free and metallophthalocyanines diazadioxamacrocycles
SUPRAMOLECULAR CHEMISTRY, cilt.17, sa.4, ss.277-281, 2005 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 17 Sayı: 4
- Basım Tarihi: 2005
- Doi Numarası: 10.1080/10610270500054051
- Dergi Adı: SUPRAMOLECULAR CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.277-281
- Anahtar Kelimeler: phthalocyanine, diazadioxamacrocycle, template effect, macrocyclization, tosylation, PHTHALOCYANINES, COMPLEXES, PHOTOSENSITIZERS, SILVER(I), LIGANDS
- Karadeniz Teknik Üniversitesi Adresli: Evet
Özet
New metal-free phthalocyanines fused in peripheral positions with eight N-monotosylated diaza-12-crown-4 macrocyclic moieties connected by diethylenethio groups have been synthesized by cyclotetramerization of a newly synthesized dicyano-substituted macrocycle. Metallophthalocyanines were also prepared by reaction of the dicyano-substituted macrocycle in the presence of corresponding metal salts and a strong organic base. The new compounds were characterized by a combination of elemental analysis, H-1 and C-13 NMR, IR, electronic and mass spectroscopies.