Titanium phthalocyanines with axial phenylenevinylenes

LYUBIMTSEV A., Misir M. N., CALVETE M., HANACK M.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, cilt.2008, sa.18, ss.3209-3214, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 2008 Sayı: 18
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1002/ejoc.200701197
  • Dergi Adı: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.3209-3214
  • Anahtar Kelimeler: titanium, phthalocyanines, axial substitution, phenylenvinylene, NONLINEAR-OPTICAL PROPERTIES, ACTIVE MATERIALS, DERIVATIVES, FILMS
  • Karadeniz Teknik Üniversitesi Adresli: Evet

Özet

The synthesis of soluble titanium(IV) phthalocyanines, axially substituted with phenylenevinylenes (PVs) (RxPcTiX), is described. The reaction of peripherally tetra- and octasubstituted (phthalocyaninato)titanium oxides (RxPcTiO) 1-3 with chelating PV-diols 4a-4c leads to the formation of axially substituted RxPcTiX 5-7. All compounds were characterized by IR, UV/Vis, MS, and H-1 NMR spectroscopy. Pcs 5-7 dissolved in dichloromethane are stable in the dark. The stability of solutions of 5-7 in sunlight depends on the nature of the peripheral substituents in the Pc ring and the chain length of the axial PV substituents. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).