Synthesis and characterisations of some new 2,4-dihydro-[1,2,4]-triazol-3-one derivatives and X-ray crystal structures of 4-(3-phenylallylideneamino)-5-thiophen-2-yl-methyl-2,4-dihydro-[1,2,4]triazol-3-one


Sancak K. , ÜNVER Y. , Kazak C., DUGDU E., Arslan B.

TURKISH JOURNAL OF CHEMISTRY, cilt.34, sa.5, ss.771-780, 2010 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 34 Konu: 5
  • Basım Tarihi: 2010
  • Doi Numarası: 10.3906/kim-0905-1
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.771-780

Özet

Compounds 2 were synthesised via the reaction of 4-amino-5-thiophen-2-yl-methyl-2,4-dihydro-[1,2,4]triazol- 3-one (1) with aldehydes. Compounds 3 and 4 were obtained from compounds 2 with bromo acetophenone and ethyl bromoacetate, respectively. The synthesis of compounds 2, 3, and 4 and crystal structure of compound 2a are being reported. The molecular structures were identified by IR, (1) H-NMR, C-13-NMR, MS, and elemental analyses. Compound 2a crystallises in the monoclinic P 21/n space group, with a = 6.565(5) angstrom, b = 18.278(5) angstrom, c = 13.8166(18) angstrom, beta = 96.227(5)., V = 1553.6(14) angstrom 3, Z = 4.