Two fluorescent silver(I)-saccharinato complexes of 2-methylpyrazine and pyrazine-2-carboxamide with Ag...Ag interactions

YILMAZ V. T., Senel E., Guney E., Kazak C.

INORGANIC CHEMISTRY COMMUNICATIONS, cilt.11, sa.11, ss.1330-1333, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 11 Sayı: 11
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1016/j.inoche.2008.08.014
  • Dergi Adı: INORGANIC CHEMISTRY COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1330-1333
  • Anahtar Kelimeler: Silver(I) complexes, Saccharinate, 2-Methylpyrazine, Pyrazine-2-carboxamide, Crystal structure, Fluorescence, COORDINATION POLYMERS
  • Karadeniz Teknik Üniversitesi Adresli: Hayır

Özet

Two new silver(I)-saccharinato (sac) complexes [Ag-4(sac)(4)(mpyz)(2)(H2O)(2)] (1), and [Ag-2(sac)(2)(pyzca)(2)] (2), (mpyz = 2-methylpyrazine, pyzca = pyrazine-2-carboxamide) have been synthesized and structurally characterized. Bridging of silver(l) centers by sac ligands results in argentophilic contacts of 3.192(1) angstrom for 1, and 3.168(2) angstrom for 2. These Ag...Ag interactions were discussed in terms of bond distances and angles around the silver(l) ion. Both complexes exhibit strong blue luminescence at room temperature in the solid state. (C) 2008 Elsevier B.V. All rights reserved.