Akkol C., Genc G., Tutal B., Uzunel İ., Saka E. T.
CATALYSTS, cilt.16, sa.6, ss.554, 2026 (SCI-Expanded, Scopus)
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Yayın Türü:
Makale / Tam Makale
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Cilt numarası:
16
Sayı:
6
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Basım Tarihi:
2026
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Doi Numarası:
10.3390/catal16060554
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Dergi Adı:
CATALYSTS
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Derginin Tarandığı İndeksler:
Academic Search Ultimate (EBSCO), Scopus, Materials Science & Engineering Collection (ProQuest), Technology Collection (ProQuest), Science Citation Index Expanded (SCI-EXPANDED), Chemical Abstracts Core, Compendex
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Sayfa Sayıları:
ss.554
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Karadeniz Teknik Üniversitesi Adresli:
Evet
Özet
Steric effects refer to the effect of the size and spatial arrangement of atoms or groups on the reactions, interactions, and catalytic activities of molecules. The incorporation of Cl (chlorine) and Br (bromine) atoms as substituents into phthalocyanine (Pc) structures can have important catalytic effects. These effects arise mainly from their electronic and steric properties, which influence the behavior of the central metal ion and the overall catalyst performance. In this work, Co(II)PcQBr2 was synthesized and characterized by spectral techniques. The catalytical activity of Co(II)PcQBr2 was then evaluated for the oxidation of benzyl alcohol. The effects of the substrate/catalyst ratio, oxidant/catalyst ratio, oxidant type and temperature on the oxidation reaction of benzyl alcohol were investigated. Both catalysts exhibited high TON, TOF and total conversion yields in the presence of H2O2 as the oxidant at 50 °C. (substrate/oxidant/catalyst:1000/500/1). When the total product conversions were calculated for both catalysts, Co(II)PcQBr2 was found to have a lower product conversion (88.7%, with a TON of 914 and a TOF of 457 ) than Co(II)PcQCl2. Moreover, Co(II)PcQCl2 was determined to have higher selectivity of benzyl benzoate (94.0%, with a TON of 940 and a TOF of 470 ). The larger size of the Br atom compared to that of the Cl atom was observed to reduce catalytic activity. Considering the size of the Cl atom, it was concluded that steric effects favor the formation of benzyl benzoate by inhibiting possible side reactions, thus increasing the catalytic activity.