trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol.64, 2008 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 64
- Publication Date: 2008
- Doi Number: 10.1107/s1600536807062745
- Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Open Archive Collection: AVESIS Open Access Collection
- Karadeniz Technical University Affiliated: No
Abstract
In the centrosymmetric title complex, [Co(C7H4NO3S)(2)(C6H15N3)(2)], the Co-II ion is coordinated by two saccharinate (sac) anions and two neutral 2-piperazin-1-ylethanamine (ppzea) ligands, showing a distorted octahedral coordination. Sac is O-bonded via the carbonyl group, while ppzea acts as an N,N'-bidentate chelating ligand. The molecules are connected by N-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds, forming a linear chain running parallel to the crystallographic a axis. The compound is isostructural with the reported Ni, Zn, and Cd analogues.