trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)

YILMAZ, VEYSEL; Guney, Serkan; Kazak, Canan

doi:10.1107/s1600536807062745

trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)

Atıf İçin Kopyala

YILMAZ V. T., Guney S., Kazak C.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.64, 2008 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 64
Basım Tarihi: 2008
Doi Numarası: 10.1107/s1600536807062745
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Karadeniz Teknik Üniversitesi Adresli: Hayır

Özet

In the centrosymmetric title complex, [Co(C7H4NO3S)(2)(C6H15N3)(2)], the Co-II ion is coordinated by two saccharinate (sac) anions and two neutral 2-piperazin-1-ylethanamine (ppzea) ligands, showing a distorted octahedral coordination. Sac is O-bonded via the carbonyl group, while ppzea acts as an N,N'-bidentate chelating ligand. The molecules are connected by N-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds, forming a linear chain running parallel to the crystallographic a axis. The compound is isostructural with the reported Ni, Zn, and Cd analogues.