10-ALPHA-HYDROXYMETHYLSPARTEINE, A NEW TYPE OF QUINOLIZIDINE ALKALOID FROM GENISTA-SESSILIFOLIA

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NASUTION M., HUSSAIN R., KINGHORN A., TOSUN A., TOSUN F., TANKER M., ...More

TETRAHEDRON LETTERS, vol.32, no.42, pp.5915-5918, 1991 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 32 Issue: 42
• Publication Date: 1991
• Doi Number: 10.1016/s0040-4039(00)79425-1
• Journal Name: TETRAHEDRON LETTERS
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Page Numbers: pp.5915-5918
• Karadeniz Technical University Affiliated: No

Abstract

10-alpha-Hydroxymethylsparteine (1), a novel type of quinolizidine alkaloid with a 16-carbon atom skeleton, was isolated from the aerial parts of Genista sessilifolia DC. The position of the hydroxymethyl substituent and the stereochemistry of compound 1 were established by analysis of its spectroscopic data.